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Direct construction of 2alkylbenzo1,3azoles via CH activation of alkanes for CC and CX (X = O, S) bond formation Arvind K Yadav and Lal DharJS Yadav* Green Synthesis Lab, Department of Chemistry, University of Allahabad, Allahabad, India Email ldsyadav@hotmailcom. 1f H S N 3f 47g 46 O O Me 1g H O N 3g 56h 45 1h O H N 3h 70i 72 a Acetylene feeding time bOther components ketoxime 2а – 4%, Nvinylpyrrole 4а – 38% c Other components Nvinylpyrrole 4b – % d Other components Nvinylpyrrole 4с – 15%. C N 3g, 19% (21% ) C N N E tO 2 C C N 3h, 10 %(87 ) C N O N E tO 2 C C O 2 E t C N 3i, 23% (39% ) C N S N E tO 2 C C N 3j, 26% () C N N E tO 2 C C N 3k, 52% C N N E tO 2 C C N 3l, 77% C N aSolvent (2mL) was added into reaction vessel charged with compound 1 (10 mmol) and 2 (12 mmol), the vessel was purged with nitrogen and them heated under reflux for 10 hours bIsolated.

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